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Synthesis, characterization and electrochemical behavior of novel mixed ligand complexes of Fe(III) with resorcinol and 2,2’-Bipyridine

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dc.contributor.author Ayalneh, Awoke
dc.date.accessioned 2023-01-12T06:19:20Z
dc.date.available 2023-01-12T06:19:20Z
dc.date.issued 2022-12
dc.identifier.uri http://ir.bdu.edu.et/handle/123456789/14880
dc.description.abstract In this study three Iron(III) complexes with resorcinol and 2,2’-biphyridine, [Fe(RH)2(H2O)4]Cl (1),[Fe(HR)2(H2O)2Bpy]Cl (2), and [Fe(RH)2(Bpy)2]Cl (3), where synthesized and characterized. The complexes where synthesized in solution and characterized using physicochemical (qualitative halide test, melting point, color and solubility), spectroscopic ( flame atomic absorption spectroscopy (FAAS), Fourier transform infrared spectroscopy(FTIR), UV Vsiblespectroscopy) as well as cyclic voltammetry. The evidences obtained from all these techniques supported the synthesis of the complexes.Based on the analytical and spectroscopic data octahedral geometry was assigned for all complexes. According to the cyclicvoltammetry results, complex 1 is reversible and less stable, whereas complex 2 and 3 are irreversible and highly stable. en_US
dc.language.iso en en_US
dc.subject Chemistry en_US
dc.title Synthesis, characterization and electrochemical behavior of novel mixed ligand complexes of Fe(III) with resorcinol and 2,2’-Bipyridine en_US
dc.type Thesis en_US


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