dc.description.abstract |
Chirality is at the origin of life and existing in nature. A system is named chiral if it is nonsuperimposable
with its own mirror image. Such object interacts with left and right circularly
polarized lights differently. The differential absorption (response) of right and left circularly
polarized light is called Circular Dichroism (CD). Finite Difference Time Domain (FDTD)
simulation method used to calculate max well equation. The purpose of this work, we are
known the chiral molecular sensing of two gold and one iron nano disks. The conventional
understanding in physics, chemistry, and biology is that circular dichroism results from
either an internal chiral structure or external symmetry breaking by illumination. We
theoretically demonstrate the existence of chirality in two dimensional and geometrically
mirror symmetric trimer nanostructures. iron oriented at the left side of the trimer nano
disks, the value of circular dichroism was different from zero (CD = 1.8%) but, the value of
circular dichroism becomes zero when iron placed at the center of the trimer nano-disks. The
trimer which contains same size two gold and one iron nanodisks were arranged
symmetrically which met the conditions of structural mirror superimposable. The optical
scattering at the fundamental resonance is characterized numerically using Finite Difference
Time Domain (FDTD) simulation method. In this approach the chiral optical response is
induced by the heterogeneous material selection. The existence of iron makes the structure
heterogeneous materially and the trimer act as super-chiral and enables the emergence of
near and far field CD in the visible regime. The result brings a paradigm shift in
understanding about the origin of chirality in science. Besides, the simplicity and generality,
this finding reveal a whole new significance of the electromagnetic design and complex
media engineering at a nanoscale with potential far-reaching implications for optics in
biology, chemistry and materials science.
Keywords: Chirality, Circular dichroism, FDTD, Gold and Iron nano sphere |
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